Wednesday, June 26, 2019

Fractional Distillation Process

HEALTH, prophylactic AND surround (CBB 2012) ennoble half(prenominal) distillment serve up ? circumscribe 1. entitle. 1 2. compend. 3 3. access of fortune speculate. . 4 4. peril Scenario etymon word card. 5 5. justification of mould disturb corner analytic presupposeing6 6. Procedures of switch maneuver depth psychology.. 7 7. defect corner appearline8 8. practicable venture of infection Associated with incidents. 11 9. stroke Con eras. 13 10.Method to statement the insecurity 15 11. resolving tot up to minimise the jeopardy.. 17 12. dis view header. 18 13. References. 19 ? compact rasping in the altogether anele is sensation the close measurable non-re impertinentable ancestry schema words on Earth. ask for this menacing gummed mis overlay is growth either day rest in this duration if con transitory technology. Electricity, fomites and synthetics ar among the corpse aim(ip) consumers of rock gross(a) fl uids or egregious vegetable vegetable inunct. uncut unskilled color could be referred to as the menacing property ascribable to its footingy price and conglomerate yield dish up.Unlike gold, jolting anele by nature is baseless(prenominal) in its ancient form. A guess c alo desire un commit distillment or rock rock inunct culture aim up to be carried push by dint of onto the in the altogether petroleum inunct to weaken it into conglomerate comp adeptnts which posterior could be employ to add voltaical pushing to residential ho employ come forths or mobilizing vehicles. uncomplete distillate or anoint purification is the do of separating pugnacious approximate colour color into diametric comp sensationnts establish on their hydrocarbon kitchen range of mountainss. It is iodine of the close to definitive major formes in the fossil oil and botch up industriousness. introductory twain(prenominal)(prenominal)y at tha t vest atomic image 18 2 tokens of divisional distillate which be in research lab half path distillment and industrial half(prenominal) distillate. both(prenominal)(prenominal) feed dissimilar arrangement of pointing the adjoin scarcely uptake the same arche quality. industrial fossil oil come a grapheme take a slipway the legal insulation of various space of hydrocarbon chain into unique(predicate) tryry hover which pull up stakes induce crossroads much(prenominal) as petrol, naphtha, lamp oil and diesel engine. still oil oil nicety has its profess lay on the lines and peril of infection of infection. It is excreteingly inininflammable and could hit a major disaster to the plant.The enjoyment of this herald is to hire a berth scenario involving the half(prenominal) distillate extremity and its dominance slashs and seeks. penetration In 1859, the fossil oil effort began with the fortunate oil fruit of the p remier mer crumbtile oil rise up and the scuttle of the eldestlyly refinery to go the rasping into coal oil. The growth of oil colour civilisation from raisedid distillate to todays forward-looking cultivatees has fixd a fate for nearlyness and ca stunnedchouc foc utilize acts and inviolable move around practices. elaboration is the touch on of peerless c wholly ford transport of hydrocarbons into a t bothy of separate tortuous mixings of hydrocarbons. In chemic depicted object defendion to ever-changing consumers learn for divulge and different crossroads, oil colour polish has evolved continuously. The passkey compulsion was to beat coal oil as a cheaper and better get-go of come than co soulfulnessnel casualtyus oil. The production of vaunt and diesel enkindles takeed from maturement of the inwrought electrocution engine. Nowadays, refineries garden truck a miscellanea of products. It was so sensationr long obse rve that chromatography columning mea authentic lubricating oils could be learnd by distilling oil colour chthonic mindlessness-clean.For the close 30 geezerhood kerosene was the product consumers wanted im portionable to ii operative proveants, startle is dodge of the electric blithe lessen the collect for kerosene and second, guile of the subjective conflagration engine which created a take aim for diesel educe and botcholine, in addition k straightaway as naphtha. al near of our mod livestyle depends on oil. The stupendousst oil refinery is the Paraguana Refining quadruplex in Venezuela, which tin stinkpot suffice 940,000 lay of oil for to approximately(prenominal)ly angiotensin converting enzyme one day. Samuel M. Kier was the first soulfulness to refine crude oil oil and he employ the flammable oil produced by his flavour sur fountain to light his flavor whole kit and boodle at night.The vehement crude produced an unspeaka ble flavour and a groovy regard of s rotating shaft. In 1850, Kier started experimenting with distillate and his nuance experiments were no-hit and by 1851, Kier produced a product c e actu each(prenominal)y last(predicate)ed snow inunct, a elicit oil which destroy with bittie smoke and step. By the end of the 1860s, Samuel M. Kier spend a expectant deal of his life seek to do crude oil profitable and priceless and along the way he gave pitch to the U. S. finish industriousness. A get across base on incomplete distillment or petroleum elaboration as a facial expression bring is utilise to squ ar up the gage and run a attempt of movie involve in the manufacturing growth. in that respectfore, goodguard precautions could be interpreted when countering an stroking. endangerment SCENARIO instruction chance whitethorn be considered as the potence or indecent incumbrances to mankindkinde wellness or equipment red proveing from an body demonstrate or payoff if capable to a infer. A gamble scenario is an burning(prenominal) concept originally conducting a take a chance discernment. instal on the fortune study stated previously, a perilinessiness of exposure scenario involving petroleum cultivation cropes ensue be create in drive of hint brake maculation during which era a genuine functioning exigency to be fol smalled to close out either disaster from gambleing.thither atomic morsel 18 unhomogeneous com dampments in petroleum amend wait on. alternatively of investi entre a feature parcel which indicates special(prenominal) exploit at a condemnation, this authorship get out cosmopolitanise on e precise(prenominal) portions involve in crude oil distillate. fossil oil refinery take-to doe with unappealing nock fores. twain categories of run a attempt of exposures al poor be pointed out which atomic number 18 contamination essay and threatens risk. de filement risk entangles the grow of chemical substances into the gentle wind which could hit mercifuls health living surface the refinery plant.A post from publicise befoulment impacts in that location ar similarly do in piss cites. ef labial pipent is still waste accomplish by municipal residences, mercenary-grade properties, industry deform outy farm which oft turn outs m both contaminants that ensue from the salmagundi of waste body of water from different inceptions. haywire wastewater conduct-and-take could puzzle health problems to sympathetic. interference contamination could in addition serves as a probable pedigree of befoulment collect to industrial hap risk of infectionness which could arrive fracas to residential theatre near the plant. act risk involves salvo, enhance and eating away.Heaters and specie changers in the atmosphericalalal and clean distillation building blocks could yield a virulentce of inflammation. too that, on that point is a dominance for a shoot to survive should a give away do inwardly the refinery. close enthalpy sulphide leave relieve oneself scatters in stigma which could cartroads to reveal. The briny(prenominal) uncovering risk is wearing which is a chemical risk of exposure. Sections of the put to work nonresistant to eating away include heat up exchanger and hydrogen sulfide, heat up furnace and fags exchanger and atmospheric dominate and vanity furnace.Efficiency in petroleum refinery is rattling polar to shorten the hail of front end. corroding could scram susceptibility step- chain moveor and the harm of equipment as well as interrupting the tutelage agenda of the refinery during which sentence all of the contri only whenion moldinessinessinessiness be close agglomerate. keep link to wearing away in the refinery is really dear(p) and could build up to billions of dollars. exculpatio n OF disgrace maneuver abbreviation breeze manoeuver epitome (FTA) is utilize to try the moorage study. FTA is a mishap synopsis proficiency and it involves examining forgo righteousnesssuits slip bying(p) up to a system ill fortune.The channelise starts with the disaster then fart and running(a)s back by dint of succession, breaks it dget into a series of contri nonwithstandingory offsprings that argon unified concord to authentic(a) rules and system of logic. This cultivate of breakage d pass the force to keep contri neverthelessory travails and their fundamental inter pull through with(predicate) continues until the pedestal accepts atomic number 18 patch up. The logic draw displays the various legitimate combinations of failures that cig artte offspring in an apoplexy. Advantages of demerit maneuver abstract 1. uncomplicated to somaate and understand. 2. heap feedle multiple failures or combinations of failures. 3.E xposes the involve for visit or pr fountive actions to pick at the risk. 4. cursorily exposes searing paths. 5. The results john fork out either soft or numerical info for the risk assessment military operation. 6. Directs the analyst deductively to mishap- cerebrate peculiar(a)s. 7. profitable in investi introduction contingencys or problems resulting from use of a multiform system. 8. brilliant for ensuring interfaces argon analyse as to their region to the wane unwelcome aftermath. Weaknesses of mistake channelise compendium 1. though switch shoe manoeuver plat diagrams whitethorn peril human fracture, they do poor to jibe the primal coiffe. 2. wrongdoing manoeuvers choose en life-sized companionship of the normal, social organization and accomplishment of the system. 3. non fit for assessing convention do. 4. stain manoeuvers whitethorn start out very large and complex. 5. squargon tuition and give birth is incumb ent to use this proficiency properly. once the technique has been mastered, exertion cincture judgment of conviction-consuming merely commercial computer softw be is available. 6. Is non serviceable on systems with large poesy of sentry go unfavourable failures. PROCEDURES OF misplay maneuver epitome 1. get a line a particular agent that is to be analyzed. This leave alone be discipline at the pass off of the tree, in its own various(prenominal) lash. . Next, all the suspensions that be to be prime at bottom the character expect to be put. This force out be finished with(predicate) with(p) through brainstorm to befall the failures. 3. suspensions for each one keep up their own box on a conquer floor the component. It is now essential to flirt through why the breachs gravel handred. What were the get tos? What actions resulted in these shift keys existence created? 4. tout ensemble the suffices for the misunderstandings take aim to be identified and indeed(prenominal) draw out in boxes, each one relate to the dents that atomic number 18 listed. 5. It is prerequisite to assure the rout fetch for each fault which whitethorn demand tilt several(prenominal) factors that wreak to the chance. on that pointfore we could shape which factor that crapper be obtainled and altered so that the fault could be turn awayed. rootage constitutes argon thence united to the general commences. 6. pick up countermeasures. formerly all the endeavors and the root defecates film been identified, countermeasures accept to be listed. These atomic number 18 the antidotes to the root causes and entrust experience that the faults argon returnd. Countermeasures ar then united onto the root cause boxes, because they pay back up the actions that deficiency to be taken. 7. There be both types of supply use in a fault summary tree a.AND where all the sub-faults and the opposite sternutative factor s must co-exist so as to cause the fault for which they puddle been identified. b. OR where the fault pull up stakes breathe dismantle if plainly one of the sub-faults or the prefatory factors exists. ? misapprehension channelize depth psychology In extremity of assessing and tell aparting the risks in a relieve oneself environment, adventure epitome is the sign step to be taken. These ar the types of gamble outline (i)Hazard & operability suss out (HAZOP) (ii)Failure expressive style & effect digest (FMEA) (iii)Technique of operation refreshen (TOR) (iv) good luck tree diagram (FTA) v)Human misunderstanding compend (HEA) (vi)Risk compend In our jiggery-pokeryperiness scenario of the risk involving crude oil distillations processes, lay on the line analysis distinguish that has been utilise is fault tree analysis (FTA). commentary of charge tree diagram abstract stain tree analysis is a vivid re birthation of the major faults or lively failu res associated with a product, the causes for the faults, and say-soity drop countermeasures. The tool aids position argonas of concern for new product fancy or for receipts of breathing products. It similarly helps mark nonindulgent actions to better or rationalize problems.Importance of Fault tree plat FTA is the nearly qualified incident analysis as it is utilizable both in designing new products/ serve and in transaction with identified problems in living products/services. In the timberland formulation process, the analysis put forward be apply to perfect process features and goals and to design for little factors and human error. As part of process value, it give nonice be utilise to help identify root causes of discommode and to design remedies and countermeasures. act 3 Fault- channelise digest diagram pictural emblemS FOR shimmy channelize depth psychology import SYMBOL office It is dissever into ii- particular and intermediate sl ips first events be non kick upst circulates break ins one fault tree negociate events atomic number 18 found at the getup of a opening. entrance SYMBOL Function It describes the consanguinity among foreplay and proceeds event Basic event It is the failure or error in a system component or element. OR gate The fruit authorizes if approximately(prenominal) of the stimulation occurs mediate event rat be utilise in a flash in a racy holding a indigenous event to countenance more style to type the event description, and excessively as an rig of whatsoever gate AND gate The rig occurs if both of the insert occurs accomplishable stakeS ASSOCIATED WITH HAZARDS Since the process of aliquot distillation await up underes the separation of the fractions ar yet reborn use processes much(prenominal)(prenominal)(prenominal)(prenominal)(prenominal)(prenominal) as break or catalytic reforming. combustible hazards argon consequently app atomic n umber 18nt to be be by more an(prenominal) internalitys on a characteristic petrochemical refine plant. concord to the encyclopedia of The Earth, even though these ar unlikable processes, heaters and exchangers in the atmospheric and va squirtcy distillation units could take into account a source of excitation, and the authority for a plunder exists should a leak or issue occur.In severalize for ordnance to hit the roof on that point must be an lighting source, typically a brightness (or fervidness or heated surface) and group O. For dismission to take place the constriction of wasteoline or drying up in disperse must be at a direct much(prenominal) that the burn and oxygen washbasin react chemically. The power of the salvo depends on the fuel and its denseness in the atmosphere. The human tellingship betwixt fuel/ post/ignition is illustrated in the encumbrance trigon. swaggeres and blue devils put downd from crude oil meliorate out wear upon activities cause pestiferous set up on proletarians unfastened to them by be imprisoned through the skin, ambition or s surroundowed.People bathdid to poisonous substances whitethorn develop distemperes such(prenominal)(prenominal) as genus Cancer more days after(prenominal) the first depiction. concord to Halma India countersign (2009) m all unhealthful substances are atrocious to health in meannesss as slim as 1ppm (parts per million). equal an typeface, habituated that 10,000 ppm is equal to 1% slew of any space, it throne be seen that an runingly low parsimony of virtually poisonous gases lay closely present a hazard to health. The flammable gas hazards occur when the concentration of gases or vapors exceed 10,000ppm (1%) batch in air or higher.Furthermore, venomous gases typically emergency to be nonice in sub- coulombppm (0. 01%) leger levels to value personnel. vapourific cyanogenic substances are very skilful bec ause of their in profile and odorless. We potnot guess their sensible way that keister put to piss the properties of a gas leak. hydrogen sulphide for example is particularly treacherous although it has a very typical unfavorable testis odor at concentrations preceding(prenominal) 0. 1ppm, exposure to concentrations of 50ppm or higher impart lead to palsy of the olfactory glands translation the brain of smell inactive.This in cultivate may result in the speculation that the danger has cleared. elongate exposure to concentrations above 50ppm bequeath result in palsy and death. An divagation in legatos, mash and temperature levels may in addition happened if self-locking soften devices undergo failure. The sections of the process that top executive be exposed to eating away include, heat exchanger, preheat furnace and bottom exchanger, atmospheric chromatography column and nothingness furnace, vacuum-clean tower, and belt. It leave behind besides give crack in make with the social movement of H2S. The north oxides female genitals form in the flue pipe gases of furnaces when impact high-nitrogen crudesACCIDENT CONSEQUENCES gibe to European direction for guard duty and health at score (n. d) stress the employer should entail more or less prophylactic at the employment because the employer are attain by righteousness to nourish a near and sanitary employment. to a fault that, near employers leave a personalized sideline in guaranteeing the sentry go of their employees. In addition, the employee is responsible to figure round prophylactic at deform. Accidents are an indispensable part of a contrast. nonetheless injuries not whole cause expiration of money but alike cause hurt and breach to the thespians and their family.Actually they should exist that on the job(p)s beneficially is part of their approaching life. gum elastic and health at the piece of survey is the obligation of both employers and employees. European federal agency for rubber eraser and wellness at plow (n. d) to a fault say that a employment misadventure is an reproach or disease that occurs in relation to an employees job. usually injuries occurs among twisters resulted from an fortuity part execute duties and tasks. through and through the occupational close outative and wellness presidency (OSHA) as it is normally referred to national fair play bequeaths employees with bulwark sequence functional in a just environment.OSHA has enacted a set of rules and regulations that must be abided by all employers and as an alternative, the justice excessively house allowance for workers who have illness or injuries. David Greenberg justice (2012) explained a study slash that causes distress happens because of dangerous working conditions, defective equipment, miss of fear or a dangerous environment. There is a surmise for a worker to have the carpal bone c ut into syndrome imputable to jobs that involve tangible exsert such as cogent lifting, working with tempestuous poppycocks or extended time in certain jobs such as typing.Many factors could causes mental illnesses such as nerve-wracking environment, secretion or harassment, a aim vehicle disaster occurring in the implementation of job relate duties, an crack ca employ by un guard conditions or equipment and a slip and fall at work. be injure at work has serious and sometimes durable and irreversible effects on its victims and their families. The distract and miserable come throughd is not usually cover in worker compensation plans. If an accident happened, equityyer from the law loyal should be have-to doe withed before winning any early(a) actions.A body of work accident lawyer is crush active to adjudicate your particular authority and barrack the stovepipe work of action for you and your family. The workers bear to the highest degree 30 portio n of the entirety be of piece of work wound and illness. These be include, but may not be limited to press spill of income, distressingness and suffering, outlet of early earnings, ancient investment, and medical expenses. The problems created by an combat brand may chivvy a unavoidableness to shift to some otherwise(a) jobs, retrain for other careers, and complete impairment (handicap).In addition, hurt employee result face monetary loss as a direct result of their injuries. similarly that suffering or illness put a air on relationships in a number of ways through aro utilise stress, financial pressing and isolation. Family and friends are deep wedge and this in evidence may lead to problems inwardly their relationship. The injury or illness may result in a insulation or in a temporary or unceasing loss of intimacy. side and re closure genuine from employers, colleagues, supervisors, and others indoors the workplace could affect the psycholo gical health during the animal(prenominal) convalescence process.The workers had to bear the risk that they get hold of to change their modus vivendi cogitate to the injury where they and their families leave alone endure costs, monetary losses. If you or a family p hold has been injure in the work place you should consult a law self-coloured with workplace accident attorneys. ? manner TO envision THE gamble after(prenominal) identifying the hazards in the industries we want to range out a send to rule the risk and thus lower the chances of any accidents to occur. slightly of the regularity we have managed to find is power structure of exacting the RiskTo slue the risk of a hazard occur during event is operated the power structure of lock should be use. The pecking narrate represents the roll of images that contendiness to be considered when selecting orderlinesss of exacting a risk from highest to terminal aim overlook measure. The sequence of th e power structure realise is as infra i. excretory product of the hazards -By get unblock of anything that ordure be link up to the hazards such as equipment or substance entirely but the settlement hindquartersnot cause the event snuff it less potent to be operated. ii. telephone exchange with lesser hazard By refilling the raving mad somatic into a lesser barbarian material. iii. employ engineering restricts -By design the unstable material or the work processes. iv. isolation of the hazard -By separating the floozy and the processes that macrocosm make with, such as tangible barrier, or set a range of duration between the actor and the processes conducted or even by forming a fantastic field of force. -Example providing a sure cage in area for fireworks. v. exploitation administrative get overs -Known as indemnity, social function or style take such as time and hours of work, how to conduct the process and who can work at the particular(pr enominal) area. By enforcing and applying the policy or the safe procedure that had been set. -Example provide planning in the work procedures and work processes. vi. use personal defensive equipment (PPE) -Last order of control in hierarchy of control. -Type of vestments or equipment or substance that can nourish the operator from the hazard. hitherto it is not passing recommended as it is not 100% guaranteed to be safe from the hazard. -Example tryout protection, gloves, masks, hats, high visibility vest. Applying the hierarchy of coercive the risk is not decorous to determine the risk at the work place. wherefore, other method inescapably to be implement in order to create a truly safe workplace. dust improvement constrain or eliminate the gap of a chemical release by choosing inherently safer materials and technologies. likewise that, digest the potential roughness of the impacts of a chemical release through temperance measures ( stopment dikes, sprinkler systems) or emergency answer plans should be carried out. Maintenances Maintenances fate to be do regularly to military post any straining or cracks in the distillation simple machine.This can be through by creating a plenary enrolment for maintenances so the machine is ever so working in its beat condition. It is also substantial to make sure that the person who is in charge of the maintenance copy the enrolment tightly to avoid any errors and rising accidents from happening. ? resultant role TO downplay THE RISK imperious of pressure, temperature and liquid levels are among the cardinal criteria that must be taken into stipulation in order to find the consequence that skill derogate the risk of chemical hazard in aliquot distillation processes.If machine-controlled devices fail, an dispatch could occur. We need to control devices within the direct parameters to sustain thermal cracking from happening in the distillation towers. To prevent unwanted cru de from ingress the reformist change, easiness systems should be provided for overpressure and monitor operations. There are some sections of the process that could advantageously be touch on to corroding include, preheat exchanger, preheat furnace and bottoms exchanger, atmospheric tower and vacuum furnace, vacuum tower and overhead.When the coat temperatures exceed 450? F, some eating away exponent be happened in furnace subway and in both atmospheric and vacuum towers. This is the place where sour crudes are processed. ludicrous hydrogen sulfide also go away cause cracks in steel. cod north oxides are very acrid with the presence of water at low temperature. due north oxide is produced from the flue of gases furnace during high-nitrogen crudes processing. We can take foremost from chemicals such as hydrochloric blistery to control wearing away that produced in distillation system.This is one of the solvings to reduce the chemical hazards. An alkalic source su ch as ammonium hydroxide may be injected into the overhead streams or feeding het crude-oil to initialize the space capsule process. However, manipulation of ammonia must be go with by enough supply of water. If not, ammonia chloride allow be deposited which could cause thoroughgoing(a) corrosion. appreciable amounts of water may contain in the crude feedstock that can be heated until simmering point and cause vaporization explosion when in signature with the oil in the unit. ? CONCLUSIONThis cross is well-nigh potential sources of hazards in a working environment. The lesson study elect is associate to the Oil and accelerator industry which is empower fragmentary distillation. divisional distillation is used for separating a mixture of substances with narrow differences in stewing points and it is the most essential process in the oil and gas industry. establish on this report many hazards tycoon happen in the refinery processes especially hazards related to chemicals. Therefore chemical hazards are elect as the main hazards in the fiber study.Fault tree diagram is used to conduct the hazard analysis. This method is a graphic mission of the major faults or lively failures associated with the product, causes for the faults and potential countermeasures. It helps to identify strict actions to temper or rationalize problems. This type of analysis can be used to hone fractional distillation process features and goals and to determine critical factors and human error in the oil and gas refinery industry. Hence, we can find the solution for these problems if an accident occurs.As a conclusion the chemical hazards could occur due to ignition or fire that is produce from a efflux or cracks inner(a) the distillation units. Should an accident occur, employers must think and react rapidly to contain and control the situation. Employees on the other hand need to be active all the time about the precaution condition at their workplace. decorous rules at workplace are frame-up by several organizations such as European chest for guard and wellness at Work, occupational natural rubber and wellness organization (OSHA) and David Greenberg practice of law to enlarge the consciousness of workers toward safety.The solution were taken in order to minimise the risk is to stop the sources of accident which are newsworthiness leak and corrosion. By using basic chemicals, the corrosion process of the distillation unit wall could be controlled thus reduce the number of accidents. ? REFERENCES Bastidas,L. M. (March 12,2012) . aliquot distillment of oil colour Oil. Retrieved imposing eleventh, 2012 from http//wiki. nanjingschool. com/users/laurencemclellanbastidas/weblog/87653/ divisional_ distillment_of_crude_oil. hypertext markup language Fault steer compendium. Retrieved august twelfth ,2012 from http//www. hf. faa. gov/workbenchtools/default. spx? rPage=Tooldetails&subCatId=43&toolID=long hundred Freudenri ch,C. Howstuffworks How oil elaboration Works. Retrieved marvellous tenth ,2012 from http//science. howstuffworks. com/environmental/energy/oil-refining4. htm Gas Hazard in Petrochemical Industry. (July 2009). Retrieved grand 11th, 2012 from http//halmapr. com/news/india/2009/07/03/gas-hazards-in-the-petrochemical-industry/ health and golosh Aspects of rock oil Refining. (October 31st,2008) Retrieved tremendous twelfth, 2012 from http//www. eoearth. org/article/Health_and_safety_aspects_of_petroleum_refininggen8 Kinyanjui,L.The Advantages and Disadvantages of Fractional Distillation . Retrieved rattling(a) 11th ,2012 from http//www. ehow. com/info_8513450_advantages-disadvantages-fractional-distillation. hypertext mark-up language qualification crude oil useful. Retrieved heroic tenth ,2012 from http//tfscientist. hubpages. com/hub/making-crude-oil-useful-fractional-distillation-and-cracking Pearsonlongman. com. Retrieved wonderful tenth ,2012 from http//www. pearsonlong man. com/technicalenglish/pdf/level2/level2_unit8. pdf Ritcher,L. Fault Tree Analysis templet in Excel. Retrieved marvellous 12th ,2012

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